Tuesday 10 November 2015

Some Heat Related Terminology

THERMODYNAMICS


  1. The branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.

  2. Heat is energy can be converted from one form to another, or transferred from one object to another. For example, a stove burner converts electrical energy to heat and conducts that energy through the pot to the water. This increases the kinetic energy of the water molecules, causing them to move faster and faster. At a certain temperature (the boiling point), the atoms have gained enough energy to break free of the molecular bonds of the liquid and escape as vapor.
  3. Specific heat

    The amount of heat required to increase the temperature of a certain mass of a substance by a certain amount is called specific heat, or specific heat capacity, according to Wolfarm Research. The conventional unit for this is calories per gram per kelvin. The calorie is defined as the amount of heat energy required to raise the temperature of 1 gram of water at 4 C by 1 degree. 
    The specific heat of a metal depends almost entirely on the number of atoms in the sample, not its mass.  For instance, a kilogram of aluminum can absorb about seven times more heat than a kilogram of lead. However, lead atoms can absorb only about 8 percent more heat than an equal number of aluminum atoms. A given mass of water, however, can absorb nearly five times as much heat as an equal mass of aluminum. The specific heat of a gas is more complex and depends on whether it is measured at constant pressure or constant volume.
  4. Thermal conductivity

    Thermal conductivity (k) is “the rate at which heat passes through a specified material, expressed as the amount of heat that flows per unit time through a unit area with a temperature gradient of one degree per unit distance,” according to the Oxford Dictionary. The unit for k is watts (W) per meter (m) per kelvin (K). Values of k for metals such as copper and silver are relatively high at 401 and 428 W/m·K, respectively. This property makes these materials useful for automobile radiators and cooling fins for computer chips because they can carry away heat quickly and exchange it with the environment. The highest value of k for any natural substance is diamond at 2,200 W/m·K.
    Other materials are useful because they are extremely poor conductors of heat; this property is referred to as thermal resistance, or R-value, which describes the rate at which heat is transmitted through the material. These materials, such as rock wool, goose down and Styrofoam, are used for insulation in exterior building walls, winter coats and thermal coffee mugs. R-value is given in units of square feet times degrees Fahrenheit times hours per British thermal unit  (ft2·°F·h/Btu) for a 1-inch-thick slab.


Newton's Law of Cooling

In 1701, Newton first stated his Law of Cooling in a short article titled "Scala graduum Caloris" ("A Scale of the Degrees of Heat") in the Philosophical Transactions of the Royal Society. Newton's statement of the law translates from the original Latin as, "the excess of the degrees of the heat ... were in geometrical progression when the times are in an arithmetical progression." Worcester Polytechnic Institute gives a more modern version of the law as "the rate of change of temperature is proportional to the difference between the temperature of the object and that of the surrounding environment." 
This results in an exponential decay in the temperature difference. For example, if a warm object is placed in a cold bath, within a certain length of time, the difference in their temperatures will decrease by half. Then in that same length of time, the remaining difference will again decrease by half. This repeated halving of the temperature difference will continue at equal time intervals until it becomes too small to measure.

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